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pH Calculator
Calculate acidity and alkalinity from hydrogen ion concentration
Reviewed by Dr. Emily Chen, Ph.D.
Analytical Chemistry Specialist | pH Measurement Expert
Last Updated: November 24, 2025
Understanding pH
pH is perhaps chemistry's most recognized measurement - from testing pool water to monitoring blood acidity. The term literally means "power of hydrogen," and it quantifies how acidic or basic (alkaline) a solution is. This logarithmic scale compresses an enormous range of hydrogen ion concentrations into an easy-to-understand 0-14 scale.
where [H⁺] = hydrogen ion concentration in mol/L
The Logarithmic Magic
Why use a logarithm? Because hydrogen ion concentrations span 14 orders of magnitude in common solutions. Battery acid contains about 1 mol/L of H⁺, while drain cleaner has only 0.00000000000001 mol/L. Rather than writing these unwieldy numbers, we use pH. The logarithm transforms the range into manageable numbers: battery acid (pH ~0) to drain cleaner (pH ~14).
The negative sign in the formula might seem odd, but it ensures higher pH means lower acidity - matching our intuition. Without the minus sign, acids would have high numbers and bases low numbers, which would be confusing.
The pH Scale Explained
pH 0-6: Acidic
- pH 0-1: Battery acid, concentrated HCl (highly corrosive)
- pH 2: Lemon juice, vinegar, stomach acid
- pH 3: Gr apefruit, orange juice
- pH 4: Tomato juice, acid rain
- pH 5: Black coffee, bananas
- pH 6: Milk, saliva
pH 7: Neutral
- Pure water at 25°C (note: exact neutrality changes with temperature)
- Blood is slightly basic at 7.35-7.45 - deviation beyond this narrow range is life-threatening
pH 8-14: Basic (Alkaline)
- pH 8: Seawater, eggs
- pH 9: Baking soda solution
- pH 10: Milk of Magnesia, laundry detergent
- pH 11: Ammonia solution
- pH 12-13: Bleach, oven cleaner
- pH 14: Liquid drain cleaner, concentrated NaOH
Real-World Applications
Swimming Pool Maintenance: Pool pH should stay between 7.2-7.8. Below 7.2 causes eye irritation and corrodes equipment. Above 7.8 reduces chlorine effectiveness and causes cloudy water. Pool operators add muriatic acid to lower pH or sodium carbonate to raise it. A single pH unit error costs pool owners hundreds in chemical waste and equipment damage.
Aquarium Keeping: Different fish species evolved in waters with different pH levels. Amazonian fish thrive in acidic water (pH 6.0-6.5), while African cichlids need alkaline conditions (pH 7.8-8.5). Sudden pH changes shock fish - even stepping from pH 7.0 to 7.5 too quickly can be fatal. Experienced aquarists monitor pH daily and make gradual adjustments.
Agriculture: Most crops prefer slightly acidic soil (pH 6.0-7.0). Below pH 5.5, aluminum becomes toxic to plants. Above pH 7.5, iron becomes unavailable, causing chlorosis (yellowing leaves). Farmers add lime to raise pH or sulfur to lower it, but soil pH changes slowly - correction takes months.
💡 Expert Tips from Dr. Chen
Temperature Affects pH: Pure water's neutral pH isn't always 7. At 0°C it's 7.47; at 100°C it's 6.14. This trips up many students. The confusion arises because Kw (water's ion product) changes with temperature, but the definition of neutrality ([H⁺] = [OH⁻]) doesn't. Always note the temperature when reporting pH.
Calibrate pH Meters Properly: I see this mistake constantly - people calibrate with one buffer and expect accuracy across the full scale. Use at least two buffers bracketing your expected range. For physiological work (pH 6-8), calibrate at pH 4, 7, and 10. Check calibration daily. A miscalibrated meter is worse than no meter because it gives you false confidence.
Dilution Doesn't Always Change pH Predictably: Students often think diluting an acid 10-fold raises pH by exactly 1 unit. This works for strong acids like HCl, but weak acids (acetic, carbonic) follow more complex behavior due to equilibrium shifts. Never assume - always measure.
⚠️ Common Mistakes to Avoid
- Confusing [H⁺] with pH: pH = 3 doesn't mean [H⁺] = 3. It means [H⁺] = 10⁻³ = 0.001 mol/L. The logarithm inverts the relationship - higher pH means lower [H⁺]. This conceptual error underlies countless calculation mistakes.
- Forgetting pH is Temperature-Dependent: A solution at pH 7.00 at 25°C won't be pH 7.00 at 50°C. The ion product of water changes, affecting equilibria. Always control and report temperature for precise work.
- Assuming All pH Paper is Equal: Wide-range pH paper (pH 1-14) is only accurate to ±1 pH unit. Narrow-range paper (e.g., pH 6-8) can achieve ±0.2 units. Match your indicator to your precision needs, or better yet, use a calibrated pH meter.
- Mixing pH and pOH: They're related (pH + pOH = 14 at 25°C) but not interchangeable. pH measures [H⁺], pOH measures [OH⁻]. Know which you're calculating and which you need.
Practical Example: Buffer Solution
You need to prepare a pH 5.0 acetate buffer. Acetic acid (CH₃COOH) has Ka = 1.8 × 10⁻⁵. What ratio of acetic acid to acetate (CH₃COO⁻) do you need?
Using Henderson-Hasselbalch Equation:
5.0 = 4.74 + log([acetate]/[acetic acid])
0.26 = log([acetate]/[acetic acid])
[acetate]/[acetic acid] = 10^0.26 = 1.82
You need 1.82 times as much acetate as acetic acid. For example, mix 0.55 M acetic acid with 1.0 M sodium acetate to achieve pH 5.0.
The Chemistry Behind pH
Water naturally dissociates into H⁺ and OH⁻ ions, though only about 1 in 10 million molecules does so at any moment. This gives pure water [H⁺] = [OH⁻] = 1.0 × 10⁻⁷ mol/L, hence pH 7.
Acids increase [H⁺] by donating protons. Strong acids (HCl, H₂SO₄) completely dissociate, while weak acids (acetic, carbonic) only partially dissociate, establishing equilibria that govern pH.
Bases decrease [H⁺] by accepting protons or providing OH⁻ ions. When you add NaOH, the OH⁻ reacts with H⁺ to form water, reducing [H⁺] and raising pH.
Understanding pH is fundamental to biochemistry (enzyme activity), environmental science (acid rain effects), medicine (respiratory acidosis), and countless industrial processes. It's a deceptively simple measurement that reveals complex molecular behavior.
Frequently Asked Questions
📚 Expert References & Further Reading
- Harris, D. C. (2015). Quantitative Chemical Analysis (9th ed.). W. H. Freeman and Company.
- Skoog, D. A., et al. (2013). Fundamentals of Analytical Chemistry (9th ed.). Brooks/Cole.
- NIST Standard Reference Database – pH Measurement. https://www.nist.gov/pml/ph-measurement
- IUPAC Recommendations for pH Measurement. https://iupac.org/
- American Chemical Society - Analytical Division Resources. https://www.acs.org/